What special brushes do
An ordinary brush has springy hair kept as long as possible so that it holds paint and lays it smoothly. Special brushes go the other way. The hair is short, stiff and trimmed flat or into a wedge, so it removes and spreads colour rather than depositing it. With a tool like that you can bring up a rivet and an edge by dry-brushing, push pigment into the corner of a wheel well, suggest worn paint on a walkway or work texture paste into a mud trail.
How to choose
By the techniques you actually use
Name the operation first. Dry-brushing wants a blunt, densely packed head that distributes colour over the high points instead of leaving it standing in beads. Chipping wants a narrow wedge you can stipple with. Pigments and texture pastes tolerate a coarser tool, because they are pushed about with real pressure.
By stiffness of hair
Stiff synthetic hair keeps its shape after hundreds of strokes and is untroubled by thinner. Softer natural hair blends powder into a finer gradient but splays sooner. If you are weighing the two up, compare synthetic brushes against natural hair brushes.
By head size
Size the head to the area, not to the scale of the model. A size 8 flat is quick and gentle over a bomber wing, while a panel in a small scale wants a head under a millimetre. Two sizes on the bench is usually the working minimum.
What to use them with
A weathering brush wears out faster than a painting brush, so treat it as a consumable and keep a spare in the jar. The full picture of shapes and sizes is in modelling brushes.